Transition-Metal Complexes of the Optically Active Cyclopentadienyl Ligand PinCp*: Crystal Structure of (SRe)-(η5-PinCp*)Re(NO)(PPh3)[CONHCH(CH3)C10H7]

1999 ◽  
Vol 1999 (9) ◽  
pp. 1497-1505 ◽  
Author(s):  
Albrecht Salzer ◽  
Annegret Hosang ◽  
Jutta Knuppertz ◽  
Ulli Englert
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Optically Active ◽  
Cyclopentadienyl Ligand

Optisch aktive Übergangsmetall-Komplexe, 122. Synthese von Palladium(II)-Schiff-Base-Komplexen -intramolekulare Wechselwirkungen / Optically Active Transition Metal Complexes, 122. Synthesis of Palladium (II) Complexes with Schiff Base Ligands -Intramolecular Interactions

2000 ◽  
Vol 55 (2) ◽  
pp. 145-154 ◽  
Author(s):  
Henri Brunner ◽  
Markus Niemetz ◽  
Manfred Zabel
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Optically Active ◽  
Intramolecular Interactions ◽  
Schiff Base Ligands ◽  
Enantiomerically Pure ◽  
Active Transition

Abstract Imines of salicylaldehyde and 2,6-diformyl-p-cresol have been used as ligands in palladium (II) complexes. Enantiomerically pure ligands give enantiomerically pure complexes, racemic ligands give racemates and meso-forms. Differences between the respective isomers of the ligands within the complexes and between the diastereomers of the complexes were investigated. Crystal structure analyses established the trans configuration at the metal center.

Sign in / Sign up

Export Citation Format

Share Document